Gas Stoichiometry
Key Questions
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Gas stoichiometry is the study of the relative amounts of reactants and products in reactions that involve gases.
EXAMPLE
Calculate the volume of gaseous NO₂ produced by the combustion of 100 g of NH₃ at 0°C and 100 kPa.Solution
Step 1. Write the balanced chemical equation.
4NH₃(g) + 7O₂(g) → 4NO₂(g) + 6H₂O(l)
Step 2. Convert mass of NH₃ → moles of NH₃ → moles of NO₂.
100 g NH₃ ×
#(1"mol NH"_3)/(17.03"g NH"_3) × (4"mol NO"_2)/(4"mol NH"_3)# = 5.872 mol NH₃ (3 significant figures +
1 guard digit)Step 3. Use the Ideal Gas Law to calculate the volume of NO₂.
#PV = nRT# #V = (nRT)/P = (5.872"mol" × 8.314"kPa·L·K"^-1"mol"^-1 × 273"K")/(100 "kPa")# = 133 L