Which of the following molecules has five σ bonds and one π bond?

(a) "C"_2"H"_6C2H6
(b) "C"_2"H"_3"Cl"C2H3Cl
(c) "C"_2"H"_2"Cl"C2H2Cl
(d) "C"_2"H"_4C2H4

1 Answer
Apr 18, 2017

The correct answer is d) "C"_2"H"_4C2H4.

Explanation:

a) "C"_2"H"_6C2H6

www.chem1.com

Ethane has six σ bonds formed by the overlap of bb"sp"^3sp3 and "s"s orbitals.

b) "C"_2"H"_3"Cl"C2H3Cl

web.chem.ucla.edu

This compound has only three σ bonds (the "C-H"C-H bonds) formed by the overlap of "sp"^2sp2 and "s"s orbitals.

c) "C"_2"H"_2"Cl"C2H2Cl

This compound does not exist.

d) "C"_2"H"_4C2H4

wps.prenhall.com

Ethylene has (i) four σ bonds formed by the overlapping of "sp"^2sp2 and "s"s orbitals;
(ii) one σ bond formed by overlapping of two "sp"^2sp2 orbital; and (iii) one π bond formed by overlap of two "p"p orbitals.