What is the molecular weight of acetic acid if a solution that contains 30.0 grams of acetic acid per kilogram of water freezes at -0.93°C. Do these results agree with the assumption that acetic acid has the formula CH3CO2H?
1 Answer
The molecular mass from this experiment is 60 u. This agrees with the value of 60.05 u calculated from the formula CH₃CO₂H.
1. Calculate the molality of the solution.
Assume that
2. Calculate the molar mass.
Molar mass =
So the molecular mass is 60 u.
You can do the above calculation in one step by rearranging the equation to read
Molar mass =
3. Compare with the known value.
The molecular mass of CH₃COOH is 60.05 u.
The experimental and the theoretical values agree within experimental uncertainty.
Here's a video on calculating the molar mass from freezing point depression.