Question #185fb

1 Answer
Sep 12, 2016

You follow a series of steps.

Explanation:

Step 1. Draw the bond-line structure of the molecule.

Bond-line

We see immediately that the longest continuous chain has 7 carbon atoms.

The correct name is 1-choro-3,5-dimethylheptane.

Step 2. Convert it to a wedge-dash structure at "C-3" and "C-4".

Wedge-Dash

Step 3. Identify the groups on "C-3" and "C-4".

The main chain of hexane is the horizontal zig-zag line of carbon atoms.

"C-1" is on the right.

The groups on "C-3" are "H", "CH"_3 and "CH"_2"CH"_2"Cl".

Those on "C-4" are "H", "H", and "CH"("CH"_3)"CH"_2"CH"_3.

Step 4. Draw a template for a Newman projection.

Newman Y

Step 5. Attach the groups to the carbons of your template.

View the molecule from the upper left.

The groups on "C-4" go on the front carbon atom. Put the "CH"("CH"_3)"CH"_2"CH"_3. group on the bottom. The two "H" atoms go on the other bonds.

The groups on "C-3" go on the back carbon. The bulky "CH"_2"CH"_2"Cl" group goes on the top. The "CH"_3 group and the "H" atom go on the other bonds.

Projection

This is the most stable conformer, because it has the bulky 2-chloroethyl and sec-butyl groups anti to each other.