Where is potential energy seen in chemistry?

1 Answer
Jun 1, 2016

The potential energy of a chemical bond is where one might see potential energy.

![http://www.mhhe.com/](useruploads.socratic.org)

On the y axis, we have the potential energy in kJ/mol, and on the x axis, we have the distance r between the left atom (H) and the right atom (H)'s nuclei.

  • As the two hydrogen atoms move closer together, the attraction between hydrogen A's valence electron and hydrogen B's proton increases. Same with hydrogen A's proton and hydrogen A's valence electron.

  • An energy of attraction is conventionally negative, so we move downwards on the potential energy curve.

If we move leftwards past the 74 pm mark on the graph:

  • When the two hydrogen atoms are too close, each proton in each nucleus repels the other. This is a nuclear repulsion energy.

  • This energy of repulsion is conventionally positive, so we move upwards on the potential energy curve.

A molecule wants to be as stable as possible; if it is unstable, it breaks apart.

So, the molecule prefers to be at the 74 pm mark, which balances the repulsive and attractive energies, giving us the potential energy of the HH single bond once the bond forms:

436 kJ/mol


This potential energy is the energy leftover, stored in the bond, after making the HH bond and releasing excess energy.

If the bond breaks, the potential energy is absorbed back into the atoms as kinetic energy as the atoms move far apart.