What is the differnce between inter esterification and trans esterification?

1 Answer
Apr 13, 2018

Here's what I get.

Explanation:

Transesterification

Transesterification is the exchange of an alkoxy group between an ester and an alcohol.

#"R"_1"CO"underbrace("-OR"_2)_color(red)("alkoxy") + "R"_3"O-H" ⇌ "R"_1"CO-"underbrace("OR"_3)_color(red)("alkoxy") + "R"_2"OH"#

The process usually involves catalysis by an acid, a base, or an enzyme.

Transesterification is the process that forms biodiesel fuel.

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Used fats and oils are triglycerides: esters of glycerol and long-chain fatty acids.

They react with methanol in the presence of a catalyst to release the glycerol and form fatty acid methyl esters (FAME), which are the components of biodiesel.

Interesterification

Interesterification is the exchange of alkyl groups between two different esters,

#"R"_1"CO-OR"_2+ "R"_3"CO""-OR"_4 ⇌ "R"_1"CO-OR"_4 + "R"_2"CO-OR"_2"#

The process usually uses acid, base, or enzyme catalysis.

The biodiesel industry also uses the interesterification process.

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The food industry uses interesterification to produce triglycerides with the desired properties (stability, melting point, etc.).

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For example, a polyunsaturated triglyceride reacts with a saturated triglyceride to form a product with intermediate properties.