What concentration of formic acid will result in a solution with #"pH" = 1.90#? The value of #K_a# for formic acid is #1.8 * 10^(−4)#
2 Answers
Explanation:
The idea here is that the
Formic acid is a weak acid, which means that it only partially ionizes to produce formate anions, the conjugate base of formic acid, and hydronium cations. For the sake of simplicity, I'll use
#"HA"_ ((aq)) + "H"_ 2"O"_ ((l)) rightleftharpoons "H"_ 3"O"_ ((aq))^(+) + "A"_ ((aq))^(-)#
As you know, the
#"pH" = - log(["H"_3"O"^(+)])#
This implies that the concentration of hydronium cations is equal to
#["H"_3"O"^(+)] = 10^(-"pH")color(white)(.)"M"#
Now, notice that in order for the ionization of the weak acid to produce
If you take
#["HA"]_ 0 = ["HA"] + ["H"_ 3"O"^(+)]#
This is equivalent to saying that in order to get an equilibrium concentration of
#["HA"] = ["HA"]_ 0 - ["H"_ 3"O"^(+)]#
Now, by definition, the acid dissociation constant is equal to
#K_a = (["H"_3"O"^(+)] * ["A"^(-)])/(["HA"])#
Since you know that, at equilibrium, you have
#["H"_3"O"^(+)] = ["A"^(-)] = 10^(-"pH")#
you can rewrite the expression you have for the acid dissociation constant as
#K_a = (["H"_3"O"^(+)]^2)/(["HA"]_0 - ["H"_3"O"^(+)])#
which is, of course, equivalent to
#K_a = (10^(-"pH"))^2/(["HA"]_0 - 10^(-"pH"))#
Rearrange to solve for the initial concentration of the formic acid
#["HA"]_0 * K_a = 10^(-2"pH") + 10^(-"pH") * K_a#
#["HA"]_0 = 10^(-2"pH")/K_a + 10^(-"pH")#
Finally, plug in your values to get
#["HA"]_ 0 = (10^(-2 * 1.90))/(1.8 * 10^(-4)) + 10^(-1.90) = color(darkgreen)(ul(color(black)("0.89 M")))#
The answer is rounded to two sig figs, the number of decimal places you have for the
The concentration is 0.89 mol/L.
Explanation:
Step 1. Calculate
Step 2. Calculate the concentration of formic acid
We can use an ICE table to organize our calculations.
Let
In this problem,
So, our ICE table becomes
Check:
It checks!