How many orbitals are found in the d sublevel?

1 Answer
Dec 3, 2015

We can derive this from knowing that the atomic orbitals each exist in accordance with angular momentum quantum number l.

Recall how l tells you the shape of the atomic orbital. That just means:

l = 0 -> s orbital
l = 1 -> p orbital
l = 2 -> d orbital
etc.

Additionally, what we have associated with l is the magnetic quantum number m_l, the projection of l in the negative, unsigned, and positive directions. In other words...

m_l = 0, pm 1, pm 2, . . . pm (l-1), pm l

If l = 2, then:

color(blue)(m_l = -2, -1, 0, +1, +2)

Each individual m_l value corresponds to a unique orbital.

That indicates that five orbitals are available in the d orbitals. Specifically, the d_(z^2), d_(x^2 - y^2), d_(xy), d_(xz), and d_(yz) orbitals.

Furthermore, from knowing that the spin quantum number m_s for an electron is pm"1/2" (two spin states), and recalling the Pauli exclusion principle (two electrons in one orbital must be opposite spins), there can be a max of two electrons per orbital.

Therefore, the total number of electrons in five orbitals can be a maximum of 10.