First consider a right angled triangle with sides 1, sqrt(3) and 2. We can tell that it is right angled because is satisfies:
1^2+sqrt(3)^2 = 1 + 3 = 4 = 2^2
Notice that this is one half of an equilateral triangle with side 2.
The angles of that equilateral triangle are all pi/3
So the smallest angle of the right angled triangle is pi/6
By definition sin pi/6 = 1/2 as that is the length (1) of the opposite side divide by the length (2) of the hypotenuse.
Now sin (-alpha) = -sin alpha, so theta = -pi/6 is a solution of sin theta = -1/2.
Also sin(pi-alpha) = sin(alpha)
So theta = pi - -pi/6 = (7pi)/6 is another solution.
sin(alpha+2npi) = sin alpha for all n in ZZ
So the solutions we have found are:
theta = -pi/6 + 2npi for all n in ZZ
theta = (7pi)/6 + 2npi for all n in ZZ