From the pythagorean identity we have that
sin^2x + cos^2x =1
Dividing both sides by cos^2x we have
tan^2x + 1 = 1/cos^2x
Which means that, if we isolate the tangent we have
tan^2x = 1/cos^2x - 1
So for x = arccos(2/3)/2 we have
tan^2(arccos(2/3)/2) = 1/cos^2(arccos(2/3)/2) -1
cos^2(arccos(2/3)/2) can be calculated using the half angle formula, so we know that
cos^2(arccos(2/3)/2) = (1+cos(arccos(2/3)))/2
Since cos(arccos(x)) = x we can say that
cos^2(arccos(2/3)/2) = (1+2/3)/2 = (5/3)/2 = 5/3*1/2 = 5/6
Putting that back on the formula
tan^2(arccos(2/3)/2) = 1/(5/6) -1 = 6/5 - 1 = (6-5)/5 = 1/5
Taking the root
tan(arccos(2/3)/2) = +-sqrt(1/5)
Knowing that during the range of the arccosine, the tangent is only negative if the cosine's also negative we have that
tan(arccos(2/3)/2) = 1/sqrt(5) = sqrt(5)/5