How do you determine pi and sigma bonds?

1 Answer
Apr 5, 2016

A sigma-bond is the first bond between two atoms, and a pi-bond is any bond in excess to that.

Explanation:

For two atoms to join they have to have at least one bond between them. This is the sigma bond.

Any bonds in excess to the sigma are called pi-bonds. For example, a double bond has one sigma and one pi, while a triple bond has one sigma and two pi. Whatever the bond, it can only ever have one sigma

On an n-bond, where n is the number of covalent bonds between two atoms, it is made of

n -> sigma + (n-1)pi