For an arbitrary nonelectrolyte, calculate the freezing point when "0.0192 mols"0.0192 mols of it is dissolved in "5.00 g"5.00 g of water? K_f = 1.86^@ "C/m"Kf=1.86C/m for water.

1 Answer
Jan 26, 2017

-7.14^@ "C"7.14C.


The idea is that dissolving anything into a solvent will decrease its freezing point. It is expected that you already know T_f^"*"T*f for water is 0^@ "C"0C, i.e. the freezing point of the pure solvent water. Therefore, you are solving for the final, lowered freezing point.

Recall:

DeltaT_f = T_f - T_f^"*" = -iK_fm

where:

  • i = 1 is the van't Hoff factor for a non-electrolyte. It simply says that only one nonelectrolyte particle exists for every nonelectrolyte particle that is placed into solution.
  • K_f = 1.86^@ "C/m" is the freezing point depression constant for water.
  • m is the molality of the solution, i.e. "mol solute"/"kg solvent".
  • T_f is the freezing point of the solution.
  • T_f^"*" is the freezing point of the pure solvent.

First, calculate what DeltaT_f would be:

DeltaT_f = -(1)(1.86^@ "C/m")(("0.0192 mols solute")/(5.00xx10^(-3) "kg H"_2"O"))

= -7.14^@ "C"

Therefore, the final freezing point is:

color(blue)(T_f) = DeltaT_f + T_f^"*" = -7.14^@ "C" + 0^@ "C" = color(blue)(-7.14^@ "C")