For an arbitrary nonelectrolyte, calculate the freezing point when "0.0192 mols"0.0192 mols of it is dissolved in "5.00 g"5.00 g of water? K_f = 1.86^@ "C/m"Kf=1.86∘C/m for water.
1 Answer
Jan 26, 2017
The idea is that dissolving anything into a solvent will decrease its freezing point. It is expected that you already know
Recall:
DeltaT_f = T_f - T_f^"*" = -iK_fm where:
i = 1 is the van't Hoff factor for a non-electrolyte. It simply says that only one nonelectrolyte particle exists for every nonelectrolyte particle that is placed into solution.K_f = 1.86^@ "C/m" is the freezing point depression constant for water.m is the molality of the solution, i.e."mol solute"/"kg solvent" .T_f is the freezing point of the solution.T_f^"*" is the freezing point of the pure solvent.
First, calculate what
DeltaT_f = -(1)(1.86^@ "C/m")(("0.0192 mols solute")/(5.00xx10^(-3) "kg H"_2"O"))
= -7.14^@ "C"
Therefore, the final freezing point is:
color(blue)(T_f) = DeltaT_f + T_f^"*" = -7.14^@ "C" + 0^@ "C" = color(blue)(-7.14^@ "C")