Question #a49bd

1 Answer
May 21, 2015

Your first reaction is actually a redox reaction (equilibrium, to be more precise) in which the silver cation, Ag^(+), oxidizes the iron (II) cations, Fe^(2+), to iron (III) cations, Fe^(3+).

In aqueous solution, the nitrate ions will act as spectator ions, so the net ionic equation will look like this

Fe_((aq))^(3+) + Ag_((aq))^(+) rightleftharpoons Fe_((aq))^(3+) + Ag_((s))

The second one is a little tricky because you have two species that do not ionize in aqueous solution, phosphoric acid, H_3PO_4, and hydrogen sulfide, H_2S.

The complete ionic equation looks like this

2H_3PO_(4(aq)) + 6Na_((aq))^(+) + 3S_((aq))^(2-) -> 3H_2S_((g)) + 6Na_((aq))^(+) + 2PO_(4(aq))^(3-)

If you eliminate the spectator ions, you'll get

2H_3PO_(4(aq)) + 3S_((aq))^(2-) -> 3H_2S_((aq)) + 2PO_(4(aq))^(3-)