Question #71458

Since you didn't give any detail about your target solution, I'll show you how to make an unsaturated, a saturated, and a supersaturated solution of potassium iodide.

Here's how potassium iodide's solubility graph looks like

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So, let's say that you want to make an unsaturated potassium iodide solution at #20^@"C"#. According to the solubility graph, you cannot dissolve more than approximately 160 g of potassium iodide per 100 mL of water.

This means that, in order to make an unsaturated solution, you need to dissolve less than 160 g of potassium iodide per 100 mL of water.

To make a saturated solution, you need to add enough potassium iodide per 100 mL of water to match the solubility at that respective temperature.

In this case, if you slowly dissolve 160 g of potassium iodide per 100 mL of water at #20^@"C"#, you'll make a saturated solution.

To get a supersaturated solution, you need to find a way to increase the amount of solvent that can be dissolved per 100 mL in your solution.

Let's say that you want your solution to dissolve as much as 180 g of potassium iodide per 100 mL of awter at #20^@"C"#.

To do that, you heat the saturated solution to, say, #40^@"C"#. At this temperature, the solution can hold a maximum of approximately 190 g of potassium iodide per 100 mL of water.

At #40^@"C"#, 180 g of potassium iodide will actually make for an unsaturated solution, since the maximum solubility at this temperature is 190 g per 100 mL.

After you dissolve 180 g of potassium iodide in the solution, you slowly cool the solution down to #20^@"C"#.

If you manage to do this correctly, the solution will now hold 180 g of potassium iodide per 100 mL of water at #20^@"C"#, i.e. it will be spersaturated.