What is a saturated solution?

1 Answer
Feb 11, 2016

Neither of the previous answers have defined a saturated solution, and would properly be rejected by an examiner. Saturation defines an EQUILIBRIUM condition.

Explanation:

A saturated solution is a solution in which the concentration of the SOLUTE is equal to that concentration that would be in equilibrium with UNDISSOLVED solute. As for any equilibrium we would normally specify a temperature (because at higher temperature, the solvent could probably dissolve more solute).

So for a water soluble salt, M^(+)X^-, we could write the following equilibrium reaction:

M^(+)X^(-)(s) stackrel(H_2O)rightleftharpoons M^(+)(aq) + X^(-)(aq).

We would probably also specify a temperature, and we could write the equilibrium condition as : K_(sp) = [M^(+)(aq)][X^(-)(aq)] (sp stands for "solubility product", and has been measured for many salts). If K_(sp) were small, what could you say with respect to the solubility of the salt?

When the ion product (i.e. [M^(+)(aq)][X^(-)(aq)] = K_(sp), the solution is said to be "saturated" with respect to MX; when the ion product > K_(sp), the solution is said to be "SUPERSATURATED", and when the ion product < K_(sp) the solution is "UNSATURATED".

These definitions are very poorly understood at undergraduate level, and I urge you to consider them and test your understanding. I reiterate that saturation defines an equilibrium condition, that has been measured for many salts at various temperatures.