20.000 mL aliquots of a phosphoric acid solution with an unknown concentration is titrated with some 0.624 mol/L sodium hydroxide solution.The average volume of the sodium hydroxide added was 24.01 mL. What is the concentration of the phosphoric acid?

1 Answer
May 31, 2017

[H3PO4]=0.375molL1.

Explanation:

We assess the reaction............

H3PO4(aq)+2NaOH(aq)Na2HPO4(aq)+2H2O(l)

Note that the phosphoric acid is A DIACID not a triacid in aqueous solution, and we use this stoichiometry accordingly.

Concentration of acid=0.624molL1×24.01×103L2×20.00×103L

=0.375molL1