Because Ar has a larger, more diffuse electron cloud than does Ne.
Explanation:
For Ne, Z=10, for Ar, Z=18. Thus argon has 8 extra electrons in a more diffuse electron cloud. The electron cloud of argon is thus more larger and more polarizable, and more able to express intermolecular dispersion forces. The result? The "boiling point" of Ar=87.2K; of Ne=24.5K.