Why do London forces occur?
1 Answer
Random fluctuations in the electron cloud of one atom/molecule induce a spontaneous dipole in an adjacent molecule, leading to a temporary attractive force between the two induced dipoles.
Explanation:
London forces are also known as Van der Waals forces or instantaneous dipole-instantaneous dipole interactions. They are present in every substance, and provide the intermolecular forces in non-polar substances.
Because electrons are constantly moving, there may be a moment when a molecule has a temporary charge imbalance across it. Since electrons repel other electrons, this charge imbalance (known as a 'dipole') can induce another dipole in a neighbouring molecule. The
London forces are very weak because they only last for a very brief period of time, but due to the incredibly large number of electrons in a substance they have a significant effect. They are stronger if there are more electrons present (for example Iodine,