Why are electrons shared equally in oxygen, O_2O2 but not in carbon monoxide COCO?

2 Answers
Feb 22, 2016

COCO is a polar molecule and O_2O2 is a non polar molecule.

Explanation:

We can answer this question by looking at the polarity of both molecules.

Oxygen, O=OO=O is a diatomic molecule that is made from two atoms of the same element, and therefore, both atoms have the same electronegativity. Thus, O_2O2 is a non polar molecule since the net dipole moment is equal to zero (sumvecmu=0μ=0).

In a non polar molecule, the electron density is equally distributed over the atoms making the molecule.

However, C-=OCO is a molecule that is made from two atoms of two different element, and therefore, the two atoms have different electronegativity. Thus, COCO is a polar molecule since the net dipole moment is not nil (sumvecmu!=0μ0).

In a polar molecule, the electron density is pulled by the more electronegative atom (which is oxygen), and therefore, the electron density is not distributed evenly on both atoms of the molecule COCO.

Feb 22, 2016

Refer to the Explanation.

Explanation:

Every element has a property called electronegativity (EN), which is the tendency of a bonded atom to attract electrons to itself. Bond character, such nonpolar and polar covalent, and ionic, is determined by the difference in electronegativities (Delta"EN").

A Delta"EN" of <0.4 indicates a nonpolar covalent bond. A Delta"EN" of 0.4-1.7 indicates a polar covalent bond, and a Delta"EN" of >1.7 indicates an ionic bond. Some authors have different guidelines, so you should always check with your instructor or your book.
http://www.chem.wisc.edu/deptfiles/genchem/sstutorial/Text7/Tx71/tx71.html

The electronegativity of an oxygen atom is 3.44. Since two oxygen atoms make up a molecule of oxygen ("O"_2"), the difference in electronegativity is abs(3.44-3.44)=0. A Delta"EN" of 0 means the bond is nonpolar covalent, and the electrons are shared equally.

The electronegativity of a carbon atom is 2.55. The Delta"EN" between carbon and oxygen is abs(2.55-3.44)=0.89. Therefore the bond is polar covalent and the electrons are not shared equally. The oxygen end will have a partial negative charge, designated by delta^-, and the carbon end will have a partial positive end, designated by delta^+.
https://en.wikipedia.org/wiki/Electronegativity#Pauling_electronegativity

http://chemwiki.ucdavis.edu/Textbook_Maps/General_Chemistry_Textbook_Maps/Map%3A_Chem1_(Lower)/08._Chemical_Bonding_and_Molecular_Structure/8.4%3A_Polar_Covalence