Which of the following molecules has the largest mass?

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Can someone explain to me how to do question 62? Thanks!

1 Answer
Mar 17, 2017

The answer is "A) 1.5 moles O"_2A) 1.5 moles O2

Explanation:

For starters, you know that diatomic oxygen, "O"_2O2, has a molar mass equal to

M_ ("M O"_2) = "32.0 g mol"^(-1)MM O2=32.0 g mol1

Now, each molecule of oxygen contains 22 atoms of oxygen, so right from the start, you can say that 11 mole of oxygen atoms will have a molar mass that is equal to half of the molar mass of diatomic oxygen

M_ ("M O") = "16.0 g mol"^(-1)MM O=16.0 g mol1

So, if 11 mole of oxygen molecules has a mass of "32.0 g"32.0 g, it follows that you will get 1/212 moles of oxygen molecules in "16.0 g"16.0 g of "O"_2O2.

Therefore, you can say that

"16 g O"_2 = 1/2color(white)(.)"moles O"_216 g O2=12.moles O2

You can use the fact that each oxygen molecule contains 22 atoms of oxygen to say that 1.24 * 10^(24)1.241024 atoms of oxygen will be equivalent to 1/2 * 1.24 * 10^(24)121.241024 molecules of oxygen.

Therefore, you have

1.24 * 10^(24)color(white)(.)"atoms O" = 6.20 * 10^(23)color(white)(.)"molecules O"_21.241024.atoms O=6.201023.molecules O2

Finally, you know that 11 mole of a molecular substance must contain 6.022 * 10^(23)6.0221023 molecules of that substance.

This means that the samples you have at point "C"C and "D"D will be equivalent to a little less than 11 mole of oxygen molecules

6.20 * 10^(23)color(red)(cancel(color(black)("molecules O"_2))) * "1 mole O"_2/(6.022 * 10^(23)color(red)(cancel(color(black)("molecules O"_2))))

= 6.20/6.022 color(white)(.)"moles O"_2

and

6.06 * 10^(23)color(red)(cancel(color(black)("molecules O"_2))) * "1 mole O"_2/(6.022 * 10^(23)color(red)(cancel(color(black)("molecules O"_2))))

= 6.06/6.022 color(white)(.)"moles O"_2

You can now say that the four samples contain

  • "A: " "1.5 moles O"_2
  • "B: " "0.5 moles O"_2
  • "C: " 6.20/6.022color(white)(.)"moles O"_2
  • "D: " 6.06/6.022 color(white)(.)"moles O"_2

Therefore, sample "A" will have the larger mass because it contains the biggest number of oxygen molecules.