Which of the following compounds is/are polar covalent: H_2OH2O, CaCl_2CaCl2, N_2N2, CH_4CH4, HNO_3HNO3? How is this determined?

1 Answer
May 24, 2017

Molecular polarity is the result of the vector sum of the individual bond dipoles..........

Explanation:

And with ionic species, because the charges are formally SEPARATED, we generally do not speak of polarity. So for CaCl_2CaCl2 we speak of an ionic salt.

On the other hand, for ""^(delta+)H-stackrel(delta-)O-Hδ+HδOH, ""^(delta+)H-stackrel(delta-)Ostackrel(+)N(=O)(-O^(-))δ+HδO+N(=O)(O) (the nitrogen is also formally quaternized), there is charge separation, polarity, and thus these are polar covalent molecules.

On the other, other hand, for N_2N2, and CH_4CH4, there is NO polarity, no charge separation, and these species are classic non-polar molecules.