What is the molar solubility of AlPO_4AlPO4?

1 Answer
Sep 28, 2016

Low. Approx. 10^-8*g*L^-1108gL1.

Explanation:

AlPO_4(s) rightleftharpoons Al^(3+) + PO_4^(3-)AlPO4(s)Al3++PO34

Now, this equilibrium is governed, i.e. quantified by the K_"sp"Ksp expression, so that:

K_"sp"Ksp == 9.84xx10^-219.84×1021 == [Al^(3+)][PO_4^(3-)][Al3+][PO34] == S^2S2

Now, since [Al^(3+)][Al3+] == [PO_4^(3-)][PO34] == SS, where SS is the solubility of aluminum phosphate, all we have to do is to solve for SS in the K_"sp"Ksp expression.

SS == sqrt(9.84xx10^-21)9.84×1021 == 9.92xx10^-11*mol*L^-19.92×1011molL1.

And we can get the solubility in grams, by forming the product:

9.92xx10^-11*mol*L^-1xx121.95*g*mol^-19.92×1011molL1×121.95gmol1 == ??g*L^-1??gL1