Why is the maximum number of (electrons, orbitals) related to each principal energy level equals 2n^22n2?
1 Answer
Because of several noticed patterns:
- There are
nn orbitals in each electron "shell". For example, then = 2n=2 shell has two types of orbitals,ss andpp . - Of the
nn orbital types (subshells), each type (which corresponds to eachll ) has2l + 12l+1 number of actual orbitals. l_max = n - 1 .
Because of that, at each energy level
...etc.
As a general rule then, the total number of orbitals in an electron "shell" is:
bb(n_"orbs") = sum_(l = 0)^(l_max) (2l + 1) = bb(sum_(l = 0)^(n - 1) (2l + 1))
If we work this out and turn it into a simpler form:
=> (2*0 + 1) + (2*1 + 1) + (2*2 + 1) + . . . + (2l_max + 1)
= (2*0) + (2*1) + (2*2) + . . . + (2l_max) + n
= 2(0 + 1 + 2 + 3 + . . . + l_max) + n
Now if we realize that the sum of the natural numbers is the last number (
=> cancel(2)([l_max*(l_max + 1)]/cancel(2)) + n
= l_max*(l_max + 1) + n
Now substitute
= (n - 1)*((n - 1) + 1) + n
= n^2 - n + n
=> color(blue)(n_"orbs" = n^2)
Therefore, the total number of orbitals in one quantum level is
Since the maximum number of electrons in each orbital is