Why is the maximum number of (electrons, orbitals) related to each principal energy level equals 2n^22n2?

1 Answer
Nov 14, 2016

Because of several noticed patterns:

  • There are nn orbitals in each electron "shell". For example, the n = 2n=2 shell has two types of orbitals, ss and pp.
  • Of the nn orbital types (subshells), each type (which corresponds to each ll) has 2l + 12l+1 number of actual orbitals.
  • l_max = n - 1.

Because of that, at each energy level n, we have the following:

n = 1: One 1s orbital, because 2(0) + 1 = bb(1)

n = 2: One 2s, three 2p orbitals, because [2(0) + 1] + [2(1) + 1] = bb(4).

n = 3: One 3s, three 3p, five 3d orbitals, because [2(0) + 1] + [2(1) + 1] + [2(2) + 1] = bb(9).

...etc.

As a general rule then, the total number of orbitals in an electron "shell" is:

bb(n_"orbs") = sum_(l = 0)^(l_max) (2l + 1) = bb(sum_(l = 0)^(n - 1) (2l + 1))

If we work this out and turn it into a simpler form:

=> (2*0 + 1) + (2*1 + 1) + (2*2 + 1) + . . . + (2l_max + 1)

= (2*0) + (2*1) + (2*2) + . . . + (2l_max) + n

= 2(0 + 1 + 2 + 3 + . . . + l_max) + n

Now if we realize that the sum of the natural numbers is the last number (l_max) plus the next number (l_max + 1), then the quantity divided by 2, we have:

=> cancel(2)([l_max*(l_max + 1)]/cancel(2)) + n

= l_max*(l_max + 1) + n

Now substitute l_max = n - 1 to get:

= (n - 1)*((n - 1) + 1) + n

= n^2 - n + n

=> color(blue)(n_"orbs" = n^2)

Therefore, the total number of orbitals in one quantum level is n^2.

Since the maximum number of electrons in each orbital is 2, the maximum number of electrons in an entire quantum level is color(blue)(2n^2).