What is the Ksp and Kf of Zn(H_2O)_6Zn(H2O)6 ?

1 Answer
Mar 26, 2017

Well K_"sp"Ksp is unknown..........

Explanation:

I think you refer to the zinc ion in water, which we should represent as [Zn(OH_2)_6]^(2+)[Zn(OH2)6]2+. Salts such as ZnCl_2ZnCl2 are mighty soluble in water (you'll have to dig for the details), but if we represent its solubility as SS,

then according to the solubility equation:

ZnCl_2(s) + "excess"H_2OrightleftharpoonsZn^(2+)+2Cl^(-)ZnCl2(s)+excessH2OZn2++2Cl

And so K_"sp"=[Zn^(2+)][Cl^-]^2Ksp=[Zn2+][Cl]2

And reasonably, we can equate the solubility of the salt, SS, with [Zn^(2+)][Zn2+]. Do you agree?

And so, finally, we write, K_"sp"=Sxx(2S)^2=4S^3Ksp=S×(2S)2=4S3.

K_"f"(Zn^(2+)(aq))Kf(Zn2+(aq)) is a trickier proposition.