What is the formal charge of N in HNO_3HNO3?

1 Answer
Apr 14, 2016

"Nitrogen has a formal +1 charge."Nitrogen has a formal +1 charge.

Explanation:

A reasonable Lewis structure is H-O-stackrel(+)N(=O)O^-HO+N(=O)O. One of the oxygen atoms has a formal negative charge, and the nitrogen atom is quaternized and bears a formal positive charge. Of course, the molecule is neutral, and the Lewis structure reflects this.

Note that when nitric acid dissociates:

HNO_3(aq) + H_2O(l) rarr H_3O^+ + NO_3^-HNO3(aq)+H2O(l)H3O++NO3

There are 3 formal charges on the nitrate ion: ""^(-)O-stackrel(+)N(=O)-O^-O+N(=O)O. The overall charge on the ion is still -11, but there is again formal charge separation in our representation of the anion.