What is the enthalpy change for the reaction #Br_2 + Cl_2 -> 2BrCl#?
1 Answer
Here's what I got.
Explanation:
From a conceptual point of view, the enthalpy change for this reaction will be equal to twice the standard enthalpy change of formation for bromine monochloride,
As you know, the standard enthalpy change of formation for a compound,
This means that the standard enthalpy change of formation will correspond to the change in enthalpy associated with this reaction
#1/2"Br"_text(2(g]) + 1/2"Cl"_text(2(g]) -> "BrCl"_text((g])#
Here
Now, the reaction given to you
#"Br"_text(2(g]) + "Cl"_text(2(g]) -> color(red)(2)"BrCl"_text((g])#
features the formation of
#2 color(red)(cancel(color(black)("moles BrCl"))) * (DeltaH_f^@)/(1color(red)(cancel(color(black)("mole BrCl")))) = color(green)(2 xx DeltaH_f^@)#
SIDE NOTE I was able to find a reference to the standard enthalpychange of formation for bromine monochloride here - page
https://books.google.ro/books?id=jSq0m9GUm4EC
The value listed here is
#DeltaH_f^@ = +"14.6 kJ/mol"#
This means that the enthalpy change for the reaction given to you will be
#DeltaH_"rxn"^@ = 2 xx "14.6 kJ/mol" = +"29.2 kJ/mol"#