What is a conjugate acid and base pair?

1 Answer
Jul 18, 2018

Conjugate acid-base pair are compounds which differ by H^+

Explanation:

Here's are two examples of conjugate acid-base pair.

OnlineClassNotes - What do you mean by conjugate acid-base pair?

The concept of conjugate acid-base pair is related to Bronsted-Lowry acid-base theory and according to this theory, acid is a proton (H^+) donor while base is a proton acceptor .

Let's focus on the first example, CH_3COOH. It behaves as an acid because it donates a proton and becomes CH_3COO^-. Imagine this:
CH_3COOH - H^+ -> CH_3COO^-

The product that is formed (CH_3COO^-) as a result of the acid, CH_3COOH donating its proton is called a conjugate base.

  • acid: CH_3COOH
  • conjugate base: (CH_3COO^-)

You might be wondering, why is CH_3COO^- called a conjugate base and not conjugate acid. Let's look at the reverse reaction. Going from CH_3COO^- -> CH_3COOH will require CH_3COO^- to accept proton, making it's a "base".

For the second example, H_2O, it behaves as a base because it accepts proton (from CH_3COOH) and becomes H_3O^+, which is the conjugate acid.

H_2O + H^+ -> H_3O^+

In this case,

  • base: H_2O
  • conjugate acid: H_3O^+

In short,

  • conjugate base is formed when an acid donates a proton.
  • conjugate acid is formed when a base accepts a proton.