What are examples of dipoles?

1 Answer
Mar 3, 2017

Any molecule that has a nonzero vector sum of dipole moments is said to be polar and have a dipole moment

Explanation:

A dipole moment refers to slight opposite charges on opposite sides of a bond. The resulting bond is said to be polar; it has a positive pole and a negative pole, much like a bar magnet.

In order to determine if a particular bond is polar or not, one must look for the electronegativity of each atom. Pauling's electronegativity is a measure of how strong a particular atom pulls electrons towards it in a bond. The value of the difference between their electronegativities (DeltaEN) determines how polar a bond is.

If:
0<= DeltaEN <=0.4, the bond is nonpolar.

0.4<DeltaEN<=1.8, the bond is polar

DeltaEN>1.8, the bond is ionic

Consider the bonds in H_2O,
https://socratic.org/questions/how-many-dipoles-are-there-in-a-water-moleculehttps://socratic.org/questions/how-many-dipoles-are-there-in-a-water-molecule

There is one oxygen bonded to two hydrogens in one water molecule. Based on the difference in electronegativites for the bonds, it is clearly a polar molecule
EN_O=3.44
EN_H=2.20
DeltaEN=3.44-2.20=1.24

In the figure above, the delta symbol indicates an area of partial charge on the atom. Note that they are not full charges as in ions, but partial charges due to a difference in electron density at each "pole". The arrow in the figure indicates the direction of electron density and the slight negative charge delta^-and the cross indicates an area of electron deficiency and the slight positive charge delta^+. This difference in charges is called a dipole moment and it is a vector quantity; it has magnitude and direction.

Notice that the water molecule has an overall dipole moment that points straight up towards the oxygen. This is because a dipole moment of a molecule depends on the vector sum of the bond dipoles.

Consider CO_2,
http://butane.chem.uiuc.edu/pshapley/GenChem2/B3/1.htmlhttp://butane.chem.uiuc.edu/pshapley/GenChem2/B3/1.html

As you can see, the DeltaEN for the C-O bond is within the polar range. However, since CO_2 is a linear molecule, the dipoles point in opposite directions and the vector sum of the two is equal to zero. CO_2 is nonpolar.