The Ksp for Fe(OH)_3 = 2.5 x 10^-20. How would you find the Ksp equation in terms of Fe^+3 and OH^- concentrations?

1 Answer
Aug 22, 2016

K_(sp)=[Fe^(3+)][HO^-]^3

Explanation:

We need (i) a chemical equation:

Fe(OH)_3(s) rightleftharpoons Fe^(3+) + 3HO^-

And (ii) a K_(sp) expression:

K_(sp)=[Fe^(3+)][HO^-]^3

Given the normal conventions, i.e. if S represents solubility etc., then,

K_(sp)=[S][3S]^3 = 27S^4 = 2.5xx10^-20.

S=""^4sqrt{(2.5xx10^-20)/(27)}

Of course hydroxide ion or iron concentration may already be artificially high.