Is there an easy way to remember the order of filling of orbitals without diagram?

1 Answer
Dec 28, 2016

Well, you'll always be given a periodic table, whether during a test or simply by looking it up, so you can use the periodic table to remember most of it. Just sit down and get to know the periodic table. Break down the patterns into chunks and remember each chunk.

![http://www.ptable.com/](useruploads.socratic.org)

In general, for the first three rows:

  • The principal quantum number n corresponds to the row number.
  • The particular block corresponds to a new angular momentum quantum number l, except for the first row.

For these three rows, the "s" block is the first two columns, and the "p" block is the last six columns.

So, we start with 1s^2, then move to row 2, which gives 2s^2 2p^6. The third row gives 3s^2 3p^6.

For the fourth and fifth rows, since we already passed n = 3, we can start talking about the 3d orbitals, so:

  • We jump down to the 3d "temporarily" after the first two 4s electrons, and jump "back up" to the six 4p electrons.
  • We jump down to the 4d "temporarily" after the first two 5s electrons, and jump "back up" to the six 5p electrons.
  • We still have that the particular block corresponds to a different angular momentum quantum number l. We just now have that the "d" block is the middle bb(10) columns, for these two rows.

So, we supposedly continue as 4s^2 3d^10 4p^6 and 5s^2 4d^10 5p^6 for the fourth and fifth rows.

We should note however that these are only expected filling orders, and not what we indefinitely see for every single heavy element!

At the sixth and seventh rows, the elements start using the f orbitals.

  • We jump down to the 4f "temporarily" after the first two 6s electrons, and jump "back up" to the ten 5d electrons and next six 6p electrons.
  • We jump down to the 5f "temporarily" after the first two 7s electrons, and jump "back up" to the ten 6d electrons and next six 7p electrons.
  • We still have that the particular block corresponds to a different angular momentum quantum number l. We just now have that the "f" block is the separate bb(14) columns, for these two rows.

So, we supposedly continue as 6s^2 4f^14 5d^10 6p^6 and 7s^2 5f^14 6d^10 7p^6.

Again, we should note however that these are only expected filling orders, and not what we indefinitely see for every single heavy element!

So, just sit down and get to know the periodic table. Break down the patterns into chunks and remember each chunk.

If you know how to read it, you can determine expected filling orders as muscle memory, and remember exceptions like "Cr", "Mo", "Cu", "Ag", and "Au".