Is C_2^+ paramagnetic or diamagnetic? Is C_2 paramagnetic or diamagnetic?
1 Answer
Apr 5, 2016
From bottom to top, we have the following valence MOs:
\mathbf(sigma_(2s)) , generated from the linear combination2s_A + 2s_B (head-on, in-phase)\mathbf(sigma_(2s)^"*") , generated from the linear combination2s_A - 2s_B (head-on, out-of-phase)\mathbf(pi_(2p_x)) , generated from the linear combination2p_(x,A) + 2p_(x,B) (sidelong, in-phase)---degenerate with (4)\mathbf(pi_(2p_y)) , generated from the linear combination2p_(y,A) + 2p_(y,B) (sidelong, in-phase)---degenerate with (3)\mathbf(sigma_(2p_z)) , generated from the linear combination2p_(z,A) + 2p_(z,B) (head-on, in-phase)\mathbf(pi_(2p_x)^"*") , generated from the linear combination2p_(x,A) - 2p_(x,B) (sidelong, out-of-phase)---degenerate with (7)\mathbf(pi_(2p_y)^"*") , generated from the linear combination2p_(y,A) - 2p_(y,B) (sidelong, out-of-phase)---degenerate with (6)\mathbf(sigma_(2p_z)^"*") , generated from the linear combination2p_(z,A) - 2p_(z,B) (head-on, out-of-phase)
You can see the compatible bonding orbital combinations here (reverse one of the orbitals' signs to achieve the corresponding antibonding orbital combination):
As a result, we have the following MO diagram (with atomic orbital energies from Inorganic Chemistry, Miessler et al., pg. 134):
Thus, with no unpaired electrons, neutral
If