Use the equation for the ideal gas law to find the moles of hydrogen gas. Then determine the mass by multiplying the moles by its molar mass.
Ideal gas law
PV=nRT
Known
P="80.1 kPa"
V="5.00 L"
R="8.31447 L kPa K"^(-1) "mol"^(-1)
T="20.0"^@"C + 273.15"="293.2 K"
Unknown
moles, n
To determine moles "H"_2", rearrange the equation to isolate n. Plug in the known values and solve.
n=(PV)/(RT)
n=(80.1color(red)cancel(color(black)("kPa"))xx5.00color(red)cancel(color(black)("L")))/(8.31447color(red)cancel(color(black)("L")) color(red)cancel(color(black)("kPa")) color(red)cancel(color(black)("K"))^(-1) "mol"^(-1)xx293.2color(red)cancel(color(black)("K")))="0.164 mol H"_2"
To determine the mass of "H"_2" by multiplying the moles by its molar mass ("2.016 g/mol").
0.164color(red)cancel(color(black)("mol H"_2))xx(2.016"g H"_2)/(1color(red)cancel(color(black)("mol H"_2)))="0.331 g H"_2"