[3 pi}/4 is 135^circ = 3 times 45^circ
Of course 30/60/90 and 45/45/90 are the only two triangles students are expected to know "exactly." We have to know the multiples of these triangles in the other quadrant. Here we have 45/45/90 in the second quadrant.
We start from cos(45^circ)=sin(45^circ)=1/sqrt{2}. The angle 135^circ is supplementary to 45^circ, so has the opposite cosine and the same sine.
cos({3pi}/4)= - cos(pi - {3pi}/4)=- cos(pi/4)= - 1/sqrt{2}
sin({3pi}/4)=sin( pi - {3pi}/4) = sin(pi/4) = 1/sqrt{2}
tan({3pi}/4) = {sin({3pi}/4)}/{cos({3pi}/4)} = {1/sqrt{2}}/{-1/sqrt{2}}=-1
sec({3pi}/4)=1/cos({3pi}/4) = - sqrt{2}
csc({3pi}/4)=1/sin({3pi}/4) = sqrt{2}
cot({3pi}/4)=1/tan({3pi}/4) = -1