How would you calculate the formal charge of CO2?

1 Answer
Nov 6, 2015

Carbon dioxide, as you know, is formally neutral; its constituent atoms are all also formally neutral.

Explanation:

::O=C=O:: is the typical Lewis structure. When we assign charge we conceive that a covalent bond is shared by the 2 participating atoms. Therefore, the central carbon shares 4 electrons with the oxygens; there are 2 inner core electrons, and thus on C there are 6 electrons that balance the 6 positively charged protons of the carbon nucleus. Carbon is neutral. For oxygen, Z=8, there are 2 lone pairs (4xxe^-) whose charge devolves solely on O, 2 e^- from the double bonds (i.e. again 1/2 of the bonding electrons), and 2 inner core electrons. Thus these 8 electrons in total balance the nuclear charge.

Can you do the same thing with nitrate anion, NO_3^-? Where does the formal negative charge lay (there is also a formal positive charge!).