We're asked to find the mass, in "g", of oxygen in 6.15xx10^23 "formula units (NH"_4")"_2"SO"_4.
To do this, we recognize that there are 4 "atoms O" per formula unit of ammonium sulfate:
6.15xx10^23cancel("formula units (NH"_4")"_2"SO"_4)((4color(white)(l)"atoms O")/(1cancel("formula unit (NH"_4")"_2"SO"_4)))
= 2.46xx10^24 "atoms O"
Now, we use Avogadro's number to find the number of moles of "O":
2.46xx10^24cancel("atoms O")((1color(white)(l)"mol O")/(6.022xx10^23cancel("atoms O"))) = ul(4.085color(white)(l)"mol O"
Finally, we use the molar mass of oxygen (15.999 "g/mol") to convert from moles to grams:
4.085cancel("mol O")((15.999color(white)(l)"g O")/(1cancel("mol O"))) = color(red)(ul(65.4color(white)(l)"g O"