How is #DeltaH_(fusion)# used to calculate the mass of solid that 1kJ of energy will melt?

1 Answer
Aug 27, 2017

With no need of a formula. Is #DeltabarH_"fus"# positive or negative for melting?


Given the enthalpy of fusion, simple unit conversion gives:

#overbrace("kJ"/"mol")^(DeltabarH_"tr") xx overbrace("mol"/"g" xx "g")^(m_"solid"//M_"solid") = overbrace("kJ")^(q)#

where #DeltabarH_"tr"# is the molar enthalpy of phase transition in #"kJ/mol"#, #q# is heat flow in #"kJ"#, #m# is mass in #"g"#, and #M# is molar mass in #"g/mol"#.

Thus:

#"g" = overbrace(cancel"kJ")^(q) xx overbrace(cancel"mol"/cancel"kJ")^(DeltabarH_"fus"^(-1)) xx overbrace("g"/cancel"mol")^(M_"solid"^(-1))#

And yet, this still refers to a real equation that we could have invoked only at constant pressure:

#q = nDeltabarH_"tr"#

where #n# is the mols of substance and #DeltabarH_"tr"# is its molar enthalpy of phase transition.