Are you asking how #pK_a# relates to pressure measurement?
Explanation:
#pK_a# relates to an equilibrium phenomenon; #mm##Hg# is a measurement of pressure. Most measurements of #pK_a# specify standard conditions, i.e. #1##atm# (#=##760##mm##Hg#), and #298##K#, but there is no real relationship between acidity and pressure.