How do you find the oxidation numbers of the elements in MnO42?

1 Answer
Feb 20, 2017

Well, it has a VI+ oxidation state if it is actually MnO24.

Explanation:

Manganate ion is MnO24, Mn(VI+).

Permanganate ion is MnO4, Mn(VII+).

In both instances, the sum of the oxidation numbers of the individual elements must equal the charge on the ion. The oxidation number of oxygen is usually II in its compounds, and it is here in both these examples.

Thus for MnO24, 4×(2)+Mnoxidation number=2.

And thus for permanganate, Mnoxidation number+4×(2)=1

I leave it up to you to solve for Mnoxidation number in each instance.

Both are known, and both are accessible oxidation states.