How do London dispersion forces increase?

1 Answer
Jun 1, 2016

Factors that affects the strength of a dispersion force include : "Distance between molecules, polarizability and the shape of the molecule."Distance between molecules, polarizability and the shape of the molecule.

Explanation:

Factors that affects the strength of a dispersion force

"Distance between molecules."Distance between molecules. Molecules must be very close together for these attractive forces to occur.

"Polarizability"Polarizability which is the ease with which an electron cloud can be deformed - larger molecules have greater number of electrons and therefore are more polarizable. This leads to stronger London dispersion forces.

"Shape of the molecule. "Shape of the molecule. The shape of the molecule (3-Dshape) affects the area available for interaction with neighboring molecules. The larger the surface area, the greater the dispersion forces. London dispersion forces between spherical molecules are smaller than those between more cylindrically shaped molecules and this is reflected in their boiling points. (e.g. pentane b.p 309.4 K and neopentane b.p 282.7.4 K).