How do I calculate vapor pressure of water?

1 Answer
Dec 20, 2014

You could use Antoine's equation to calculate the vapor pressure of water. Antoine's equation is a vapor pressure equation that describes the relationship between vapor pressure and temperature for pure components. So,

log_10p = A - B/(C + T)log10p=ABC+T, where

pp - the vapor pressure;
TT - temperature;
AA, BB, CC - constants specific to each substance.

You'd get p = 10^(A-B/(C + T))p=10ABC+T.

This equation is usually used with two sets of paramaters, a low-pressure paramater that describes the vapor pressure curve up to the normal boiling point, and a second paramater that covers the range from boiling point to critical point.

So, for water, the two sets of paramaters are

SET 1. AA = 8.07131, BB = 1730.63, CC = 233.426 for temeperatures between 11 and 100^@C100C;
SET 2. AA = 8.14019, BB = 1810.94, CC = 244.485 for temperatures betwen 9999 and 374^@C374C.

Notice that you can use both sets of paramaters for temeperatures between 9999 and 100^@C100C.

Here's a diagram of what an Antoine curve would look like

![http://en.wikipedia.org/wiki/Vapor_pressure](useruploads.socratic.org)