For any substance, why does temperature remain constant during change of state?

1 Answer
Jun 28, 2017

Because a condition of phase equilibrium applies during change of state.

Explanation:

For the thermodynamic processes......

H2O(s)H2O(l) at 0 C and....

H2O(l)H2O(g) at 100 C .....

.........these occur under equilibrium conditions. Energy has to be supplied to break the (strong) bonds between the molecules of the condensed phase; for water, this so-called latent heat of fusion or latent heat of vaporization are quite large and reflects the degree of INTERMOLECULAR force between the individual molecules (i.e. a consequence of hydrogen bonding).