Diphosphorus pentoxide reacts with water to produce phosphoric acid (H3PO4). How do you write the balanced equation for this reaction?

1 Answer
Jan 15, 2016

P4O10(s]+6H2O(l]4H3PO4(aq]

Explanation:

The interesting thing about diphosphorus pentoxide, P2O5, is that it usually exists as a dimer.

This implies that P2O5 is actually the compound's empirical formula and that you should use P4O10 as its molecular formula.

Now, diphosphorus pentoxide reacts violently with water to form phosphoric acid, H3PO4. The reaction is highly exothermic and leads to the formation of toxic fumes.

The unbalanced chemical equation for this reaction looks like this

P4O10(s]+H2O(l]H3PO4(aq]

To balance this equation, start by multiplying the phosphoric acid by 4 to get equal numbers of atoms of phosphorus on both sides of the equation

P4O10(s]+H2O(l]4H3PO4(aq]

Notice that you have 2 atoms of hydrogen on the reactants' side and 12 on the products' side. Multiply the water molecule by 6 to balance the hydrogen atoms out.

Incidentally, this will also balance out the atoms of oxygen, since you'd now have 16 on the reactants' side and 16 on the products' side.

The balanced chemical equation for this reaction will thus be

P4O10(s]+6H2O(l]4H3PO4(aq]

It's worth mentioning that diphosphorus pentoxide is a very powerful dehydrating agent.

SIDE NOTE You'll sometimes see this reaction written using the empirical formula of diphosphorus pentoxide, P2O5. In that case, the balanced chemical equation will be

P2O5(s]+3H2O(l]2H3PO4(aq]