Boric acid is written as H3BO3 or B(OH)3...but if it is written as B(OH)3...why is it still an acid and not a base?
2 Answers
In fact most oxyacids have hydroxyl functions...
Explanation:
Consider nitric acid, i.e.
Any resonance isomer of the nitrate anion has 3 atoms with formal charge. But the parent is manifestly an hydroxide....
And we could got to a stronger acid...
As written this is another hydroxide..
Of course the sulfate anion is resonance stabilized but I think you get the idea. Are you happy with this....? And of course there is also
And so another generalization....the hydroxides of non-metals feature fairly weak bonds between hydrogen and the oxygen...on the other hand, for metal hydroxides, the
It can accept electron density into the empty
Those
#2"H"_2"O"(l) rightleftharpoons "H"_3"O"^(+)(aq) + cancel("OH"^(-)(aq))#
#ul("B"("OH")_3(aq) + cancel("OH"^(-)(aq)) rightleftharpoons "B"("OH")_4^(-)(aq))#
#"B"("OH")_3(aq) + 2"H"_2"O"(l) \rightleftharpoons "B"("OH")_4^(-)(aq) + "H"_3"O"^(+)(aq)#
#K_(a,L) = 7.3 xx 10^(-10)#
So the equilibrium constant for the addition of
Or, since it has
#"B"("OH")_3(aq) + "H"_2"O"(l) rightleftharpoons "BO"("OH")_2^(-)(aq) + "H"_3"O"^(+)(aq)# or
#"H"_3"BO"_3(aq) + "H"_2"O"(l) rightleftharpoons "H"_2"BO"_3^(-)(aq) + "H"_3"O"^(+)(aq)#
#K_(a,BL) = 5.8 xx 10^(-10)#
However, it's not much of a Bronsted-Lowry acid (