Aluminum, #"Al"#, produces #"H"_2# bubbles when immersed in #"HCl"#, mercury, #"Hg"# does not. Which is the strongest reducer?
A) Al3+
B) Al
C) Hg
D)Hg+
E H2
A) Al3+
B) Al
C) Hg
D)Hg+
E H2
1 Answer
Aluminium metal.
Explanation:
Basically, the fact that aluminium produces bubbles of hydrogen gas when immersed in hydrochloric acid tells you that it can reduce hydrochloric acid to hydrogen gas.
#2"Al"_ ((s)) + 6"HCl"_ ((aq)) -> 2"AlCl"_ (3(aq)) + 3"H"_ (2(g)) uarr#
The oxidation half-reaction looks like this
#"Al"_ ((s)) -> "Al"_ ((aq))^(3+) + 3"e"^(-)#
So aluminium metal acts as a reducing agent here because each atom of aluminium loses
The reduction half-reaction looks like this
#2"H"_ ((aq))^(+) + 2"e"^(-) -> "H"_ (2(g))#
Here, each atom of hydrogen gains
You can balance the number of electrons lost and gained in the two half-reactions to get the overall balanced chemical equation that describes this redox reaction.
So aluminium is the reducing agent because it reduces hydrogen cations,
By comparison, mercury does not produce bubbles of hydrogen gas when immersed in hydrochloric acid, so it cannot reduce hydrochloric acid to hydrogen gas.
So if the metal cannot reduce hydrochloric acid to hydrogen gas, the mercury(I) cation,