A saturated solution of PbBr_2 is prepared by dissolving the solid salt in water. The concentration of Pb_2^+ in solution is found to be 0.0115 M. What is the Ksp for PbBr_2?

1 Answer
Jul 14, 2017

K_(sp)=6.1xx10^-6

Explanation:

We interrogate the solubility equilibrium.........

PbBr_2(s) rightleftharpoonsPb^(2+) + 2Br^(-)

Now K_(sp)=[Pb^(2+)][Br^-].........And if we say that the solubility of PbBr_2-=S, then by stoichiometry........

K_(sp)=[S][2S]^2=4S^3 (because S=[Pb^(2+)], and [Br^-]=2S

=4xx(0.0115)^3=6.1xx10^-6.........

Can you define what is meant by a "saturated solution......?"