A 0.01 M solution of an acid has a pH = 5.0. What is the Ka value?
1 Answer
Explanation:
I'm assuming that you're working with a monoprotic weak acid here so that the ionization equilibrium can be written like this
#"HA"_ ((aq)) + "H"_ 2"O"_ ((l)) rightleftharpoons "A"_ ((aq))^(-) + "H"_ 3"O"_ ((aq))^(+)#
Now, you know that the solution has
#"pH" = 5#
As you know, the
#color(blue)(ul(color(black)("pH" = - log(["H"_3"O"^(+)]))))#
You can rearrange this equation to find the equilibrium concentration of hydronium cations.
#log(["H"_3"O"^(+)]) = - "pH"#
This is equivalent to
#10^log(["H"_3"O"^(+)]) = 10^(-"pH")#
which gets you
#["H"_3"O"^(+)] = 10^(-"pH")#
In your case, you will have
#["H"_3"O"^(+)] = 10^(-5.0) = 1.0 * 10^(-5)# #"M"#
Now, notice that every mole of
This means that, at equilibrium, the solution has
#["A"^(-)] = ["H"_3"O"^(+)] " "-># produced in a#1:1# mole ratio
In your case, you have
#["A"^(-)] = 1.0 * 10^(-5)# #"M"#
The initial concentration of the acid will decrease because some of the molecules ionize to produce
So, in order for the ionization to produce
This means that, at equilibrium, the concentration of the weak acid will be equal to
#["HA"] = ["HA"]_"initial" - ["H"_3"O"^(+)]#
In your case, you will have
#["HA"] = "0.01 M" - 1.0 * 10^(-5)color(white)(.)"M"#
#["HA"] = "0.00999 M"#
By definition, the acid dissociation constant,
#K_a = (["A"^(-)] * ["H"_3"O"^(+)])/(["HA"])#
Plug in your values to find
#K_a = (1.0 * 10^(-5)color(red)(cancel(color(black)("M"))) * 1.0 * 10^(-5)color(white)(.)"M")/(0.00999color(red)(cancel(color(black)("M"))))#
#K_a = 1.001 * 10^(-8)# #"M"#
Rounded to one significant figure and expresses without added units, the answer will be
#color(darkgreen)(ul(color(black)(K_a = 1 * 10^(-8))))#