Question #eae43
2 Answers
The percent ionization of salicylic acid is approximately
Explanation:
This is basically an equilibrium problem where you know the initial concentration (a usual one). But your cited
[Your cited
Write the reaction first, so you have a way to organize:
#"HC"_7"H"_5"O"_3(aq) rightleftharpoons "C"_7"H"_5"O"_3^(-)(aq) + "H"^(+)(aq)#
#"I"" "["HC"_7"H"_5"O"_3]_i" "" "" ""0 M"" "" "" "" ""0 M"#
#"C"" "" "-x" "" "" "" "" "+x" "" "" "+x#
#"E"" "["HC"_7"H"_5"O"_3]_(i) - x" "x" M"" "" "" "" "x" M"#
METHOD 1: USING THE
Next, apparently we know
If you want to use a solubility, you must cite its temperature.
#color(green)(["HC"_7"H"_5"O"_3]_(i) = (2.48 cancel"g")/"L" xx "1 mol"/(138.12 cancel("g H"_7"H"_5"O"_3))#
#=# #color(green)("0.0179"_6 "M")#
Using your cited
#K_a = 1.06 xx 10^(-3) = x^2/("0.01796 M" - x)#
Solving for the quadratic form,
#x^2 + 1.06 xx 10^(-3) x - 1.06 xx 10^(-3) cdot 0.01796 = 0# ,and the result is
#x = ul(["H"^(+)]_(eq) = "0.00387 M")# from the quadratic formula.
The percent dissociation is
#color(blue)(%"dissoc") = x/(["HA"]_i) xx 100%#
#= ("0.00387 M")/("0.0179"_6 "M" + "0.00387 M") xx 100%#
#= color(blue)ul(17.7%)#
And that's reasonable. Salicylic acid has a non-negligible percent dissociation with a
METHOD 2: TRYING THE pH (this won't work)
With the
#10^(-"pH") = ul(["H"^(+)]_(eq)) = x = 10^(-4.96) "M" = ul(1.10 xx 10^(-5) "M")#
As before, the solubility was
This is pretty big in comparison to
#color(red)(%"dissoc") = x/(["HA"]_i) xx 100%#
#= (10^(-4.96) "M")/("0.0179"_6 "M") xx 100% = color(red)(0.0611%)# which doesn't make sense how low this is, given the size of
#K_a# .
In fact, the
#color(red)(K_a) = (10^(-4.96) "M")^2/("0.0179"_6 "M" - 10^(-4.96)"M") = color(red)(6.70 xx 10^(-9))# ,which is far from the actual.