Question #412b9
1 Answer
Here's what I got.
Explanation:
The first thing to notice here is that copper is being reduced from copper(II) cations to copper(I) cations, which implies that nitrogen is being oxidized in this redox reaction.
More specifically, the oxidation number of nitrogen goes from
Also, notice that you have some protons present on the products' side; this tells you that the reaction is taking place in acidic medium.
So, start with the reduction half-reaction, which looks like this
#stackrel(color(blue)(+2))("Cu") ""_ ((aq))^(2+) + "e"^(-) -> stackrel(color(blue)(+1))("Cu") ""_ ((aq))^(+)#
Each copper(II) cations gains
#(2+) + (1-) -> (1+)#
The oxidation half-reaction looks like this
#stackrel(color(blue)(+4))("N")"O"_ (2(aq)) -> stackrel(color(blue)(+5))("N")"O"_ (3(aq))^(-) + "e"^(-)#
Here each nitrogen atom loses
In order to balance the atoms of oxygen, add water molecules to the side that needs oxygen and protons,
In your case, you will have
#"H"_ 2"O"_ ((l)) + stackrel(color(blue)(+4))("N")"O"_ (2(aq)) -> stackrel(color(blue)(+5))("N")"O"_ (3(aq))^(-) + "e"^(-)+ 2"H"_ ((aq))^(+)#
The half-reaction is balanced in terms of charge because you have
#0 -> (1-) + (1-) + 2 xx (1+)#
You can thus say that the two half-reactions are
#{(color(white)(aaaaa)stackrel(color(blue)(+2))("Cu") ""_ ((aq))^(2+) + "e"^(-) -> stackrel(color(blue)(+1))("Cu") ""_ ((aq))^(+)), ("H"_ 2"O"_ ((l)) + stackrel(color(blue)(+4))("N")"O"_ (2(aq)) -> stackrel(color(blue)(+5))("N")"O"_ (3(aq))^(-) + "e"^(-)+ 2"H"_ ((aq))^(+)) :}#