Question #1a680
1 Answer
Explanation:
You know that an unknown reducing agent will reduce sodium nitrate to ammonia, so start by looking at the reduction half-reaction.
Keep in mind that you don't need to balance the half-reaction because you're only interested in how the oxidation state of nitrogen changes!
#stackrel(color(blue)(+5))("N") "O"_ 3""^(-) + 8"e"^(-) -> stackrel(color(blue)(-3))("N")"H"_ 3#
Now, notice that the oxidation state of nitrogen goes from
This means that the
Now, in every redox reaction, the number of electrons lost in the oxidation half reaction must be equal to the number of electrons gained in the reduction half-reaction.
In your case, you know that
#7.65 * 10^(-3) color(red)(cancel(color(black)("moles NaNO"_3))) * "8 e"^(-)/(1color(red)(cancel(color(black)("mole NaNO"_3)))) = 6.12 * 10^(-2)# #"moles e"^(-)#
Since you know that the reaction consumed
#1 color(red)(cancel(color(black)("mole reducing agent"))) * (6.12 * 10^(-2)color(white)(.)"moles e"^(-))/(3.06 color(red)(cancel(color(black)("moles reducing agent")))) = "2 moles e"^(-)#
Since every
#ncolor(white)(.)"factor reducing agent" = 2#
SIDE NOTE I would try to balance the reduction half-reaction like this--the reaction takes place in basic medium!
#9"H"_ 2"O" + stackrel(color(blue)(+5))("N") "O"_ 3""^(-) + 8"e"^(-) -> stackrel(color(blue)(-3))("N")"H"_ 3 + 3"H"_2"O" + 9"OH"^(-)#