What is osmotic pressure, and what is it dependent on?
1 Answer
Jul 4, 2017
Osmotic pressure is the pressure that needs to be applied to one side of a semi-permeable membrane to prevent solvent flow across the membrane into the more concentrated side, and is given by:
Pi = iMRT ,where:
i is the van't Hoff factor for the solute(s), i.e. the effective number of particles in solution per formula unit.M is the solution concentration in... well,"mol/L" , molarity,"M" .Pi is the osmotic pressure in"atm" , ifR is the universal gas constant in"L"cdot"mol/atm"cdot "K" .T is temperature in"K" , as usual.
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Thus, osmotic pressure is dependent on
- the electrolytic features of the solute (the stronger the electrolyte, the more particles per formula unit, and thus the higher the
Pi needed to stop a larger number of solute particles from sucking up the solvent) - the concentration of the solution on one side of the membrane (the higher it is, the greater the
Pi needed to stop a higher concentration of solute from sucking up the solvent) - the temperature of the solution (the higher it is, the greater
Pi is to stop the faster solvent flow in warmer environments)
These are all direct proportionalities, i.e. as